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1.
J Phys Chem Lett ; 13(29): 6831-6838, 2022 Jul 28.
Artigo em Inglês | MEDLINE | ID: mdl-35857895

RESUMO

We study the influence of a linear energy bias on a nonequilibrium excitation on a chain of molecules coupled to local vibrations (a tilted Holstein model) using both a random-walk rate kernel theory and a nonperturbative, massively parallelized adaptive-basis algorithm. We uncover structured and discrete vibronic resonance behavior fundamentally different from both linear response theory and homogeneous polaron dynamics. Remarkably, resonance between the phonon energy ℏω and the bias δϵ occurs not only at integer but also fractional ratios δϵ/(ℏω) = m/n, which effect long-range n-bond m-phonon tunneling. These observations are reproduced in a model calculation of a recently demonstrated Cy3 system, and the effect of dipole-dipole-type non-nearest-neighbor coupling and vibrationally relaxed initial states is also considered. Potential applications range from molecular electronics to optical lattices and artificial light harvesting via vibronic engineering of coherent quantum transport.

2.
Phys Rev Lett ; 116(8): 086403, 2016 Feb 26.
Artigo em Inglês | MEDLINE | ID: mdl-26967431

RESUMO

We present evidence for Mott quantum criticality in an anisotropic two-dimensional system of coupled Hubbard chains at half-filling. In this scenario emerging from variational cluster approximation and cluster dynamical mean-field theory, the interchain hopping t_{⊥} acts as a control parameter driving the second-order critical end point T_{c} of the metal-insulator transition down to zero at t_{⊥}^{c}/t≃0.2. Below t_{⊥}^{c}, the volume of the hole and electron Fermi pockets of a compensated metal vanishes continuously at the Mott transition. Above t_{⊥}^{c}, the volume reduction of the pockets is cut off by a first-order transition. We discuss the relevance of our findings to a putative quantum critical point in layered organic conductors, whose location remains elusive so far.

3.
Phys Rev Lett ; 110(7): 075301, 2013 Feb 15.
Artigo em Inglês | MEDLINE | ID: mdl-25166378

RESUMO

Recent theory has indicated how to emulate tunable models of quantum magnetism with ultracold polar molecules. Here we show that present molecule optical lattice experiments can accomplish three crucial goals for quantum emulation, despite currently being well below unit filling and not quantum degenerate. The first is to verify and benchmark the models proposed to describe these systems. The second is to prepare correlated and possibly useful states in well-understood regimes. The third is to explore many-body physics inaccessible to existing theoretical techniques. Our proposal relies on a nonequilibrium protocol that can be viewed either as Ramsey spectroscopy or an interaction quench. The proposal uses only routine experimental tools available in any ultracold molecule experiment. To obtain a global understanding of the behavior, we treat short times pertubatively, develop analytic techniques to treat the Ising interaction limit, and apply a time-dependent density matrix renormalization group to disordered systems with long range interactions.

4.
Phys Rev Lett ; 111(26): 260401, 2013 Dec 27.
Artigo em Inglês | MEDLINE | ID: mdl-24483785

RESUMO

We study the nonequilibrium dynamics of correlations in quantum lattice models in the presence of long-range interactions decaying asymptotically as a power law. For exponents larger than the lattice dimensionality, a Lieb-Robinson-type bound effectively restricts the spreading of correlations to a causal region, but allows supersonic propagation. We show that this decay is not only sufficient but also necessary. Using tools of quantum metrology, for any exponents smaller than the lattice dimension, we construct Hamiltonians giving rise to quantum channels with capacities not restricted to a causal region. An analytical analysis of long-range Ising models illustrates the disappearance of the causal region and the creation of correlations becoming distance independent. Numerical results obtained using matrix product state methods for the XXZ spin chain reveal the presence of a sound cone for large exponents and supersonic propagation for small ones. In all models we analyzed, the fast spreading of correlations follows a power law, but not the exponential increase of the long-range Lieb-Robinson bound.

5.
Phys Rev Lett ; 109(20): 205305, 2012 Nov 16.
Artigo em Inglês | MEDLINE | ID: mdl-23215502

RESUMO

Ultracold fermionic alkaline earth atoms confined in optical lattices realize Hubbard models with internal SU(N) symmetries, where N can be as large as ten. Such systems are expected to harbor exotic magnetic physics at temperatures below the superexchange energy scale. Employing quantum Monte Carlo simulations to access the low-temperature regime of one-dimensional chains, we show that after adiabatically loading a weakly interacting gas into the strongly interacting regime of an optical lattice, the final temperature decreases with increasing N. Furthermore, we estimate the temperature scale required to probe correlations associated with low-temperature SU(N) magnetism. Our findings are encouraging for the exploration of exotic large-N magnetic states in ongoing experiments.

6.
Phys Rev Lett ; 108(12): 127202, 2012 Mar 23.
Artigo em Inglês | MEDLINE | ID: mdl-22540619

RESUMO

We show that spin S Heisenberg spin chains with an additional three-body interaction of the form (S(i-1)·S(i))(S(i)·S(i+1))+H.c. possess fully dimerized ground states if the ratio of the three-body interaction to the bilinear one is equal to 1/[4S(S+1)-2]. This result generalizes the Majumdar-Ghosh point of the J1-J2 chain, to which the present model reduces for S=1/2. For S=1, we use the density matrix renormalization group method to show that the transition between the Haldane and the dimerized phases is continuous with a central charge c=3/2. Finally, we show that such a three-body interaction appears naturally in a strong-coupling expansion of the Hubbard model, and we discuss the consequences for the dimerization of actual antiferromagnetic chains.

7.
Phys Rev Lett ; 107(11): 115301, 2011 Sep 09.
Artigo em Inglês | MEDLINE | ID: mdl-22026682

RESUMO

By selecting two dressed rotational states of ultracold polar molecules in an optical lattice, we obtain a highly tunable generalization of the t-J model, which we refer to as the t-J-V-W model. In addition to XXZ spin exchange, the model features density-density interactions and density-spin interactions; all interactions are dipolar. We show that full control of all interaction parameters in both magnitude and sign can be achieved independently of each other and of the tunneling. As a first step towards demonstrating the potential of the system, we apply the density matrix renormalization group method to obtain the 1D phase diagram of the simplest experimentally realizable case. Specifically, we show that the tunability and the long-range nature of the interactions in the t-J-V-W model enable enhanced superfluidity. Finally, we show that Bloch oscillations in a tilted lattice can be used to probe the phase diagram experimentally.

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